Europe - Champions League
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by Daniel Ngulu | in Champions League Predictions
Greek giants Olympiacos and their Dutch counterparts PSV are set to face off in the fourth round of matches in the Champions League. This match will mark the first ever meeting between them in this competition, but they’ve faced off before in the Europa League. That was back in 2020/21 in the knockout stages when Olympiacos advanced after a 5-4 aggregate win. This one will be hosted by Olympiacos, and below we have a prediction.
The home team hasn’t lost to a Dutch side across the last seven home matches against such opposition. This will be a key stat for Olympiacos, who look to better their performances at the league/group stage.
PSV, on their part, have managed 10 wins in their 15 matches against Greek opponents. Only four of those 15 ended in defeat, and they’ll hereby look to frustrate Olympiacos’ search for a first win in the Champions League this season. With four points, PSV are 16th in the standings, while Olympiacos are 33rd.
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The Best Betting Odds for Olympiacos v PSV Eindhoven Match
| Bookmaker | 1 | X | 2 | Bonus up to |
|---|---|---|---|---|
|
2.6 | 3.7 | 2.55 |
|
|
2.5 | 3.75 | 2.63 |
|
|
2.45 | 3.5 | 2.62 |
|
|
2.5 | 3.6 | 2.6 |
|
|
2.55 | 3.65 | 2.6 |
|
What is the prediction for the football match between Olympiacos and PSV Eindhoven?
Our prediction for the Olympiacos vs PSV Eindhoven match is: BTTS.
Probabilities according to our algorithm* of possible 1X2 football predictions and best odds for the match on 04/11/2025 between Olympiacos and PSV Eindhoven in Champions League :
- The Sportytrader ⭐ algorithm estimates a probability of 39.44% for a win of Olympiacos against PSV Eindhoven with odds of 2.6 at Bet365.
- The probability according to Sportytrader ⭐ for a draw between Olympiacos vs PSV Eindhoven is 15.28% with odds of 3.75 at Betfred.
- Our prediction model gives a 45.28% chance ⭐ for a win of PSV Eindhoven vs Olympiacos with odds of 2.63 at Betfred.
Olympiacos - PSV Eindhoven Prediction and Best Odds:
| Olympiacos PSV Eindhoven Prediction | Probability | Odds |
|---|---|---|
| PSV Eindhoven wins | 45.28% | 2.63 at Betfred |
| Over 2.5 goals | 69.93% | 1.49 at Bwin |
| Both Team To Score | 60.42% | 1.45 at Betway |
| Half-time / Full-time: PSV Eindhoven/PSV Eindhoven | 17.06% | 4.2 at Ladbrokes |
Olympiacos vs PSV Eindhoven Form
Olympiacos and PSV Eindhoven's standings in the Champions League
| Teams | Pts | P | W | D | L | GD |
|---|---|---|---|---|---|---|
|
18
|
5 | 4 | 1 | 2 | 1 | 2 |
|
31
|
2 | 4 | 0 | 2 | 2 | -7 |
Olympiacos and PSV Eindhoven Last Matches
4/6 (67%)
0/6 (0%)
2/6 (33%)
Average stats (Last 6 matchs)
1 Nov 2025 - Superleague
29 Oct 2025 - Greece Cup
26 Oct 2025 - Superleague
21 Oct 2025 - Champions League
18 Oct 2025 - Superleague
5 Oct 2025 - Superleague
5/6 (83%)
1/6 (17%)
0/6 (0%)
Average stats (Last 6 matchs)
1 Nov 2025 - Superleague
29 Oct 2025 - Greece Cup
26 Oct 2025 - Superleague
27 Sept 2025 - Superleague
17 Sept 2025 - Champions League
13 Sept 2025 - Superleague
2/6 (33%)
1/6 (17%)
3/6 (50%)
Average stats (Last 6 matchs)
21 Oct 2025 - Champions League
18 Oct 2025 - Superleague
5 Oct 2025 - Superleague
1 Oct 2025 - Champions League
24 Sept 2025 - Greece Cup
21 Sept 2025 - Superleague
5/6 (83%)
1/6 (17%)
0/6 (0%)
Average stats (Last 6 matchs)
31 Oct 2025 - Eredivisie
26 Oct 2025 - Eredivisie
21 Oct 2025 - Champions League
18 Oct 2025 - Eredivisie
4 Oct 2025 - Eredivisie
1 Oct 2025 - Champions League
3/6 (50%)
1/6 (17%)
2/6 (33%)
Average stats (Last 6 matchs)
31 Oct 2025 - Eredivisie
21 Oct 2025 - Champions League
18 Oct 2025 - Eredivisie
21 Sept 2025 - Eredivisie
16 Sept 2025 - Champions League
30 Aug 2025 - Eredivisie
5/6 (83%)
1/6 (17%)
0/6 (0%)
Average stats (Last 6 matchs)
26 Oct 2025 - Eredivisie
4 Oct 2025 - Eredivisie
1 Oct 2025 - Champions League
27 Sept 2025 - Eredivisie
13 Sept 2025 - Eredivisie
17 Aug 2025 - Eredivisie
Olympiacos vs PSV Eindhoven Stats: Head to Head (H2H)
50 %
0 %
50 %
Average stats (last H2H results)
25 Feb 2021 - Europa League
18 Feb 2021 - Europa League
Olympiacos - PSV Eindhoven: Form Analysis
Olympiacos haven't had a great start in Europe and will come here on a winless run of three matches in the league phase. They will hope for a matchday four rise as they return home following two difficult away trips.
They did start with a home game, drawing 0-0 with debutants Pafos. The Greeks managed to score for the first time this season, but that ended in a 6-1 defeat in Barcelona. The loss came off the heels of a matchday two 2-0 fall at Arsenal.
There is some hope they can cling on here, having gone unbeaten in the last seven home games against Dutch opponents.
However, in group/league stage matches, they’ve managed just two wins in 23 in the Champions League, losing 18.
PSV have scored 20 times in their last five matches, all of them being wins.
PSV have grown from strength to strength in the Champions League since their shock opening defeat to Union SG. They recovered from it with a 1-1 away draw at Bayer Leverkusen.
Their return home was even better, as they thrashed Italian champions Napoli 6-2 on matchday three. The Dutch giants only have to show similar performances on their away days, and they will be good to go.
Rood-witten have struggled a bit on the road in this competition, winning just once in the last eight. In the eight matches after their loss to Union SG, PSV are unbeaten, winning six.
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Olympiacos against PSV Eindhoven Lineups: Starting 11
Formation : 4 - 2 - 3 - 1
Formation : 4 - 3 - 3
Olympiacos & PSV Eindhoven Squad Analysis
For all his impact on the Olympiacos team, Daniel Podence has this season had trouble scoring. That, however, eased in the 2-1 win at home to Aris on Saturday.
He scored the opening goal in the game to end a nine-match goal drought. In his imperious shape in that game, he also laid on the assist for the second goal.
The Portuguese forward also went close in matchday two action against Arsenal and will hope to carry on here. Each of his last four goals for Olympiacos has been accompanied by an assist.
Olympiacos’ Santiago Hezze will miss this game due to suspension.
The most likely first goal scorer for PSV has been Ismael Saibari. The Moroccan youngster has given PSV the lead in four of the last eight matches.
He has scored in seven of the Dutch side’s last eight games, a total of 10 goals. Two of his goals came in this competition, having netted one each against Bayer Leverkusen and Napoli.
In his last two matches alone, Saibari netted five goals, and the visitors will be placing a lot of hopes on his shoulders.
Most goals and assists
Olympiacos
PSV Eindhoven
A. El Kaabi
(9 Goals)
I. Saibari
(10 Goals)
D. Podence
(3 Assists)
J. Veerman
(7 Assists)
Olympiacos - PSV Eindhoven Key Points
- Both sides scored in PSV’s last four matches.
- Olympiacos scored in all of their last five matches.
- PSV recorded only one clean sheet in their last 10 matches.
- In the two earlier meetings between these sides, both scored.
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Our Olympiacos vs PSV Eindhoven Prediction
Olympiacos will hope playing at home elevates their chances of a first win in the Champions League this season. They were poor in their opening home game of this competition, while they were dominated in the next two.
However, they will have renewed belief here, seeing that they’ve only failed to score once at home. The Greeks meet a PSV side on a similarly good scoring run. PSV have shown struggles in defence and that could extend here. Our prediction for Olympiacos v PSV is BTTS.
Olympiacos vs PSV Eindhoven - Other Interesting Predictions
Draw
PSV are coming off a fine run and will hope to take it to nine matches without defeat. This ambition is well powered by a streak of five straight wins. The Dutchmen will be justified to feel as favorites coming into this encounter.
However, they will meet a resolute host, also determined to bring order to their European campaign. Olympiacos are doing well at home, and it takes some effort from PSV to break them. As two in-form sides face off, we predict a draw.
Last Minute: Pre-match odds analysis Olympiacos PSV Eindhoven
| Olympiacos vs PSV Eindhoven | Opening odds | Pre-match odds | Odds Movements |
|---|---|---|---|
| Olympiacos wins | 2.3 | 2.6 | +13.0% |
| Draw | 3.5 | 3.7 | +5.7% |
| PSV Eindhoven wins | 3 | 2.55 | -15.0% |
After kick-off, the latest odds movements show that:
- PSV Eindhoven is most likely to win
- The odds for this bet have decreased by 15.0% since opening
- The probability of this result was 33.3% and is now 39.2% (5.9%)
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Olympiacos vs PSV Eindhoven match : Frequently asked questions
The Olympiacos v PSV match will be played on Tuesday, November 5th.
The Olympiacos v PSV match will be aired on Cosmote TV and AlterEgo for Greek followers. Those in the Netherlands can watch the match on Ziggo Sport. SportyTrader will also have the UEFA Champions League match updates.
Clement Turpin from France has been named the Olympiacos v PSV match referee.
All tips are fully researched and given in good faith, but profits cannot be guaranteed.
