Villarreal vs Napoli Prediction & Picks - Champions League

Europe - Champions League

Villarreal
10/13/26 15:00
Napoli

Prediction:

 

Both Teams to Score

-175
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 by Bradley Gibbs | in Champions League Picks

The second round of UEFA Champions League fixtures is upon us, and in this game, two teams who came unstuck during the opening set of League Phase games will lock horns at Estadio de la Ceramica. The hosts lost to Dortmund of the German Bundesliga, while the men from Napoli suffered defeat against the current English Premier League champions. Both teams have been scoring and conceding regular goals this season, so this looks like a game that is very much there for the taking, but which team will step up? 

There appears to be a strong chance of both teams notching at least once in this game, a stronger chance even than odds of -175 (= 63.6% implied probability) indicate. Both teams have been scoring regularly, especially in their respective home and away games, while there's no reason for either team to view this as anything but a game to attack. 

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Villarreal vs Napoli Form

Table

Teams Pts P W D L GD
21 Villarreal
0 1 0 0 1 -1
27 Napoli
0 1 0 0 1 -1

Villarreal and Napoli Latest Matches

Villarreal
Villarreal Latest matches
L L L W W L
Victories

2/6 (33%)

Draw

0/6 (0%)

Defeats

4/6 (67%)

Average stats (Last 6 matchs)

3.67 Total goals
83% BTTS
1.83 Goals scored
1.83 Goals conceded
83% Over 2.5
17% Under 2.5

Oct 10, 2026 - LaLiga

Real Madrid
1 :  0
Villarreal

Sep 20, 2026 - LaLiga

Villarreal
3 :  1
Levante

Sep 17, 2026 - LaLiga

Málaga
1 :  3
Villarreal

Sep 14, 2026 - LaLiga

Villarreal
1 :  2
Betis

Sep 8, 2026 - Champions League

Borussia Dortmund
3 :  2
Villarreal

Sep 5, 2026 - LaLiga

Villarreal
2 :  3
La Coruna
L W W L L W
Victories

3/6 (50%)

Draw

0/6 (0%)

Defeats

3/6 (50%)

Average stats (Last 6 matchs)

4 Total goals
83% BTTS
2.33 Goals scored
1.67 Goals conceded
83% Over 2.5
17% Under 2.5

Sep 20, 2026 - LaLiga

Villarreal
3 :  1
Levante

Sep 14, 2026 - LaLiga

Villarreal
1 :  2
Betis

Sep 5, 2026 - LaLiga

Villarreal
2 :  3
La Coruna

Aug 5, 2026 - Clubs Friendlies

Villarreal
1 :  0
Levante

May 24, 2026 - LaLiga

Villarreal
5 :  1
Atletico Madrid

May 13, 2026 - LaLiga

Villarreal
2 :  3
Sevilla
D D L L W L
Victories

1/6 (17%)

Draw

2/6 (33%)

Defeats

3/6 (50%)

Average stats (Last 6 matchs)

3.17 Total goals
67% BTTS
1.5 Goals scored
1.67 Goals conceded
67% Over 2.5
33% Under 2.5

Oct 10, 2026 - LaLiga

Real Madrid
1 :  0
Villarreal

Sep 17, 2026 - LaLiga

Málaga
1 :  3
Villarreal

Sep 8, 2026 - Champions League

Borussia Dortmund
3 :  2
Villarreal

Aug 28, 2026 - LaLiga

Alavés
1 :  0
Villarreal

Aug 23, 2026 - LaLiga

Atletico Madrid
2 :  2
Villarreal

Aug 16, 2026 - LaLiga

Racing Santander
2 :  2
Villarreal
Napoli
Napoli Latest matches
L L L W D W
Victories

2/6 (33%)

Draw

1/6 (17%)

Defeats

3/6 (50%)

Average stats (Last 6 matchs)

2.5 Total goals
50% BTTS
1.33 Goals scored
1.17 Goals conceded
50% Over 2.5
50% Under 2.5

Oct 10, 2026 - Serie A

Napoli
3 :  0
Frosinone

Sep 20, 2026 - Serie A

Fiorentina
1 :  1
Napoli

Sep 13, 2026 - Serie A

Napoli
1 :  0
Bologna

Sep 9, 2026 - Champions League

Napoli
0 :  1
Arsenal

Sep 5, 2026 - Serie A

Inter Milan
3 :  2
Napoli

Aug 30, 2026 - Serie A

Napoli
1 :  2
Como 1907
D W L L W W
Victories

3/6 (50%)

Draw

1/6 (17%)

Defeats

2/6 (33%)

Average stats (Last 6 matchs)

3 Total goals
50% BTTS
2 Goals scored
1 Goals conceded
50% Over 2.5
50% Under 2.5

Oct 10, 2026 - Serie A

Napoli
3 :  0
Frosinone

Sep 13, 2026 - Serie A

Napoli
1 :  0
Bologna

Sep 9, 2026 - Champions League

Napoli
0 :  1
Arsenal

Aug 30, 2026 - Serie A

Napoli
1 :  2
Como 1907

Aug 12, 2026 - Clubs Friendlies

Napoli
6 :  2
Aris Thessaloniki

Aug 8, 2026 - Clubs Friendlies

Napoli
1 :  1
Celta Vigo
D D W W L D
Victories

2/6 (33%)

Draw

3/6 (50%)

Defeats

1/6 (17%)

Average stats (Last 6 matchs)

2.33 Total goals
50% BTTS
1.5 Goals scored
0.83 Goals conceded
33% Over 2.5
67% Under 2.5

Sep 20, 2026 - Serie A

Fiorentina
1 :  1
Napoli

Sep 5, 2026 - Serie A

Inter Milan
3 :  2
Napoli

Aug 22, 2026 - Serie A

Genoa
0 :  2
Napoli

May 17, 2026 - Serie A

Pisa SC
0 :  3
Napoli

May 2, 2026 - Serie A

Como 1907
0 :  0
Napoli

Apr 12, 2026 - Serie A

Parma
1 :  1
Napoli
Villarreal vs Napoli Picks

Napoli v Villarreal last Lineups

Villarreal

Formation : 5 - 3 - 2

25
P. Gulacsi
3
A. Freeman
6
P. Navarro
8
J. Foyth
12
R. Veiga
23
S. Cardona
14
S. Comesana
18
P. Gueye
10
A. Moleiro
22
A. Perez
11
I. Akhomach
70
N. Lang
19
R. Hojlund
7
D. Neres
37
L. Spinazzola
68
S. Lobotka
11
K. De Bruyne
22
G. Di Lorenzo
5
B. Badiashile
13
A. Rrahmani
16
R. Marin
1
A. Meret

Formation : 3 - 4 - 3

Napoli

Substitutes

Villarreal
Villarreal
Goalkeeper

L. Junior

Defender

L. Costa

S. Mourino

C. Romero

Midfielder

C. Macia

N. Saliba

A. Diatta

Forward

G. Moreno

G. Mikautadze

T. Oluwaseyi

N. El Jmili

J. Gaitan

Napoli
Napoli
Goalkeeper

V. Milinkovic-Savic

N. Contini

Defender

L. Marianucci

S. Beukema

Midfielder

S. Mctominay

B. Gilmour

Forward

Giovane

M. Pereyra

L. Lucca

M. Politano

Missing players

Villarreal
Villarreal
Forward

T. Buchanan

Napoli
Napoli
Defender

M. Olivera

A. Buongiorno

Midfielder

F. Anguissa

A. Vergara

C. Favasuli

Forward

A. Santos

Villarreal and Napoli Stats in Champions League

Villarreal
Villarreal
Napoli
Napoli
0%
Wins
0%
100%
Losses
100%
0%
Draws
0%
5
Average goals per match
1
2
Goals scored per match
0
3
Goals conceded per match
1
0%
Under 2.5 goals
100%
100%
Over 2.5 goals
0%
0%
No goals conceded
0%
100%
Both score
0%

Villarreal - Napoli Key Points

  1. Both teams scored in Villarreal's last home game.
  2. Both teams also scored in Napoli's last away game.
  3. Both teams have found the net in each of Villarreal's three competitive home games this season.
  4. In all competitions, both teams have scored in five of Villarreal's last six games.
  5. Neither the hosts nor the visitors kept a clean sheet during the first round of UCL League Phase games.
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Our Villarreal vs Napoli Prediction

The visitors have been scoring regular road goals this season, so they really should fancy themselves to go to Estadio de la Ceramica and do some damage. The problem for the Italians is that they've struggled to defend of late, and if their last couple of away-day defensive efforts are anything to go by, then they'll likely find it rather tough to keep things tight at the back in Spain. 

If we also consider the frequency with which the hosts have scored and conceded in games, a game where both teams find the net at least once simply looks more likely than the early odds imply. 

Our Villarreal vs Napoli Pick: Both Teams to Score.

Prediction:

 

Both Teams to Score

-175
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All tips are fully researched and given in good faith, but profits cannot be guaranteed.